Factors affecting the functioning of solid state fluoride galvanic cells
نویسنده
چکیده
Fluoride galvanic cells employing CaF2 as electrolyte have not been as extensively employed for thermodynamic characterization of alloys and compounds as the oxide electrolyte cells based on stabilized zirconia. However, CaF 2 galvanic cells have many advantages over oxide electrolyte cells. These advantages, as well as the factors affecting the proper functioning of the CaF2 cells, are discussed, highlighting the experimental aspects, such as the interference by the gas phase, choice of the reference electrode, and the volatility and compatibili ty of the materials.
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